Sediment source fingerprints of natural processes and anthropogenic pressures: A contribution to manage the Paraopeba River basin impacted by the B1 tailings dam collapse.

Understanding the origins of sediment transport in river systems is crucial for effective watershed management, especially after catastrophic events. This information is essential for the development of integrated strategies that guarantee water security in river basins. The present study aimed to investigate the rupture of the B1 tailings dam of the Córrego do Feijão mine, which drastically affected the Brumadinho region (Minas Gerais, Brazil). To address this issue, a confluence-based sediment fingerprinting approach was developed through the SedSAT model. Uncertainty was assessed through Monte Carlo simulations and Mean Absolute Error (MAE). Estimates of the overall average contributions of each tributary were quantified for each station and annually during the period 2019-2021. It was observed that the sampling point PT-09, closest to the dam breach, contributed to almost 80% of the Paraopeba River in 2019. Despite the dredging efforts, this percentage increased to 90% in 2020 due to the need to restore the highly degraded area. Additionally, the main tributaries contributing to sediment increase in the river are Manso River "TT-03" (almost 36%), associated with an area with a high percentage of urban land use, and Cedro stream "TT-07" (almost 71%), whose geology promotes erosion, leading to higher sediment concentration. Uncertainties arise from the limited number of available tracers, variations caused by dredging activities, and reduced data in 2020 due to the pandemic. Parameters such as land use, riparian vegetation degradation, downstream basin geology, and increased precipitation are key factors for successfully assessing tributary contributions to the Paraopeba River. The obtained results are promising for a preliminary analysis, allowing the quantification of key areas due to higher erosion and studying how this disaster affected the watershed. This information is crucial for improving decision-making, environmental governance, and the development of mitigating measures to ensure water security. This study is pioneering in evaluating this methodology in watersheds affected by environmental disasters, where restoration efforts are ongoing.

Beyond land use planning and ecosystem services assessment with the conservation use potential framework: A study in the Upper Rio das Velhas basin, Brazil.

Human actions can damage the ecosystems and affect the services depending on them, with ample detrimental consequences. In earlier studies, the Conservation Use Potential (PCU) framework proved useful in assessing the capacity for aquifer recharge, suitable land uses and resistance to erosion at the river basin scale. On the other hand, the joint analysis of PCU and land uses allowed identifying the adequacy of current uses in relation to suitability (natural uses) in various basins. This was especially useful from the management perspective in basins with environmental conflicts, where current uses differed from suitability, because the PCU indicated how and where the conflicts should be mitigated. Besides the use as management tool, the PCU has potential to shed light over environmental issues such as ecosystem services, but that was not tempted so far. The aim of this work was therefore to bridge that knowledge gap and frame the PCU's application from the standpoint of Ecosystem Services (ES) assessment. We demonstrated how the PCU could be used to improve provision (recharge), support (sustainable agriculture) and regulation (resistance to erosion) services in a specific basin with land use conflicts (the Upper Rio das Velhas basin, located in Minas Gerais, Brazil), through the planning of suitable uses. It was noted that the studied basin is mostly composed of Very Low, Low and Medium potentials. These classes occur because steep slopes, fragile soils and lithologies with high denudation potential and low nutrient supply dominate in the basin. On the other hand, urban sprawl has a negative impact on all ES, while maintaining agricultural areas with appropriate management can effectively regulate erosion. As per the current results, the premise of using the PCU as joint management-environmental tool was fully accomplished, and is recommended a basis for public policy design and implementation in Brazil and elsewhere.

Geomorphologic risk zoning to anticipate tailings dams' hazards: A study in the Brumadinho's mining area, Minas Gerais, Brazil.

The use of tailings dams in the mining industry is recurrent and a matter of concern given the risk of collapse. The planning of tailings dam's emplacement usually attends construction design criteria and site geotechnical properties, but often neglects the risk of installing the depositional facilities in potentially unstable landscapes, namely those characterized by steep slopes and(or) high drainage densities. In order to help bridging this gap, the present study developed a framework model whereby geomorphologic vulnerability is assessed by a set of morphometric parameters (e.g., drainage density; relief ratio; roughness coefficient). Using the Ribeirão Ferro-Carvão micro-basin (3265.16 ha) as test site, where six dams currently receive tailings from the mining of iron-ore deposits in the Brumadinho region (Minas Gerais, Brazil) and one has collapsed in 25 January 2019 (the B1 dam of Córrego do Feijão mine of Vale, S.A.), the risk of dam instability derived from geomorphologic vulnerability was assessed and alternative suitable locations were highlighted when applicable. The results made evident the location of five dams (including the collapsed B1) in high-risk regions and two in low-risk regions, which is preoccupying. The alternative locations represent 58 % of Ribeirão Ferro-Carvão micro-basin, which is a reasonable and workable share. Overall, the study exposed the fragility related with tailings dams' geography, which is not restricted to the studied micro-basin, because dozens of active tailings dams exist in the parent basin (the Paraopeba River basin) that can also be vulnerable to geomorphologically-dependent hydrologic hazards such as intensive erosion, valley incision or flash floods. Attention to this issue is therefore urgent to prevent future tragedies related with tailings dams' breaks, in the Paraopeba River basin or elsewhere, using the proposed framework model as guide.

Groundwater security indicators and their drivers: An assessment made in a region of tropical climate (Paraopeba River basin, Brazil).

Groundwater helps overcoming periods of drought buffering their effects on water supply to people, natural ecosystems and the economy. Following the latest Conference of the Parties (COP27), groundwater research gained renewed impulse because the Parties committed themselves to invest on environmental dimensions of water security related with aquifer characterization and protection. In that context, the purpose of this study was to help providing an integrated assessment to some fundamental issues about groundwater security, summarized as the three "how"s: how much, how ready and for how long can groundwater be delivered from watersheds? A complementary goal was to identify and quantify the role of watershed characteristics controlling these "how"s. The methodology combined hydrologic modeling and GIS and the results for the test site (Paraopeba River basin, Brazil) were: (1) the studied river tributaries mostly drain regolith aquifers with short hydrologic turnover times (1.3-23.7 yr) and small aquifer mobile storages (0.1-1.3 m), but high specific yields (0.2-8.2 m/yr), being generally prone to hydrologic droughts; (2) the specific discharge is primarily elevation controlled (via precipitation increases with altitude), but relates positively with drainage density as well; (3) the mobile storage in the Quadrilátero-Ferrífero mountain is larger than elsewhere, being influenced by a local geomorphologic setting (higher coverage with concave hillslopes); (4) the groundwater contribution to streamflow discharge is high (> 50 %, on average), being improved with the coverage of argisols; (5) vulnerability to droughts could be alleviated through expansion of water-retention infrastructure in specific regions, as well as through land use conversions targeting reduced evapotranspiration or sustainable land management of argisol and concave surface landscapes. Although applied to a specific catchment, our results stand on a site-independent methodological framework. Thus, the understanding about groundwater security gained with this study can be inspiring to other workers dealing with tropical climate landscapes.

Payment for Environmental Services: A critical review of schemes, concepts, and practice in Brazil.

The Payment for Environmental Services (PES) is often conceived through complex schemes without a clear definition of all concepts involved. This study presents the results of a systematic literature review on PES schemes in Brazil, accompanied by a critical assessment of their efficacy for potential environmental gains. The PES approaches were grouped into six categories based on the research focus, and those that were focused on PES policies were identified as the most studied. A particular emphasis has been given to the Amazon and Atlantic Forest biomes, where the ecosystem services studied were mostly centered on issues related to carbon and water, respectively. Approximately one-third of all schemes provided no clear definition of which ecosystem services are proposed for payment. In addition, the review showed no consensus among studies on the definition of services in similar schemes. Most schemes presented no payment system conditioned on the provision of environmental services. Furthermore, the review showed that the absence of clarity in the application of concepts may hinder the development of public policies to properly implement PES in Brazil. The conclusion is that standardizing terms used in the literature and in PES schemes is critical; therefore, the use of the Common International Classification of Ecosystem Services (CICES) as a reference is recommended to ensure clarity, objectivity and, more importantly, the expected environmental efficacy.

Scenarios of environmental deterioration in the Paraopeba River, in the three years after the breach of B1 tailings dam in Brumadinho (Minas Gerais, Brazil).

The collapse of B1 dam at the Córrego do Feijão mine of Vale, S.A., located in the Ferro-Carvão stream watershed (Brazil), released 11.7 Mm3 of tailings rich in iron and manganese, and 2.8 Mm3 entered the Paraopeba River 10 km downstream. Seeking to predict the evolution of environmental deterioration in the river since the dam break on January 25, 2019, the present study generated exploratory and normative scenarios based on predictive statistical models, and proposed mitigating measures and subsides to ongoing monitoring plans. The scenarios segmented the Paraopeba into three sectors: "anomalous" for distances ≤63.3 km from the B1 dam site, "transition" (63.3-155.3 km), and "natural" (meaning unimpacted by the mine tailings in 2019; >155.3 km). The exploratory scenarios predicted a spread of the tailings until reaching the "natural" sector in the rainy season of 2021, and their containment behind the weir of Igarapé thermoelectric plant located in the "anomalous" sector, in the dry season. Besides, they predicted the deterioration of water quality and changes to the vigor of riparian forests (NDVI index) along the Paraopeba River, in the rainy season, and a restriction of these impacts to the "anomalous" sector in the dry season. The normative scenarios indicated exceedances of chlorophyll-a in the period January 2019-January 2022, but not exclusively caused by the rupture of B1 dam as they also occurred in areas not affected by the accident. Conversely, the manganese exceedances clearly flagged the dam failure, and persist. The most effective mitigating measure is likely the dredging of the tailings in the "anomalous" sector, but currently it represents solely 4.6 % of what has entered the river. Monitoring is paramount to update the scenarios until the system enters a route towards rewilding, and must include water and sediments, the vigor of riparian vegetation, and the dredging.

Multicriteria spatial model to prioritize degraded areas for landscape restoration through agroforestry.

Reconciling the restoration of ecosystem services within agricultural landscapes is an effort that has been advancing within degraded areas restoration through agroforestry systems. However, to contribute to the effectiveness of these initiatives, it is essential to integrate landscape vulnerability and local demands to better highlight in which areas the implementation of agroforestry systems should be prioritized. Thus, we developed a spatial hierarchization methodology as a decision support tool as an active strategy for agroecosystem restoration. The proposed method constitutes a spatial indicator of priority areas to guide agroforestry interventions, including resource allocation and public policies for payment for environmental services. The methodology consists of Multicriteria Decision Analysis implemented in GIS software by combining input datasets based on biophysical conditions, environmental and socioeconomic aspects, that integrated promotes an assessment of the environment fragility, the pressures and responses to land use dynamic; a strategy for landscape restoration and conservation of the natural habitats, and multiple specific scenarios for decision making regarding the agricultural and the local actors demands. The output of the model provides the spatial distribution of areas suitable for the implementation of agroforestry systems, sorted into four priority levels (Low, Medium, High, and Extreme priority). The method is a promising tool proposal for territorial management and governance and subsidizes future research on the flows of ecosystem services.•Assessment of the environment fragility and the pressures and responses to land use dynamic.•Strategy for landscape restoration and conservation of remaining natural habitats.•Multiple specific scenarios for decision making regarding the agricultural and the local actors demands.

The COP27 screened through the lens of global water security.

Water security is an expression of resilience. In the recent past, scientists and public organizations have built considerable work around this concept launched in 2013 by the United Nations as "the capacity of a population to safeguard sustainable access to adequate quantities of acceptable quality water for sustaining livelihoods, human well-being, and socio-economic development, for ensuring protection against water-borne pollution and water-related disasters, and for preserving ecosystems in a climate of peace and political stability". In the 27th Conference of the Parties (COP27), held in Sharm El-Sheikh (Egypt) in last November, water security was considered a priority in the climate agenda, especially in the adaption and loss and damage axes. This discussion paper represents the authors' opinion about how the conference coped with water security and what challenges remain to attend. As discussion paper, it had the purpose to stimulate further discussion in a broader scientific forum.

A framework model to determine groundwater contamination risk based on a L-Matrix of aquifer vulnerability and hazardous activity indices.

The method presented in this study assesses groundwater contamination risk using a L-Matrix system approach. The L-Matrix in this case is a cartesian diagram where the XX-axis represents aquifer vulnerability (0≤V≤1) determined by the well-known DRASTIC model, and the YY-axis represents the potential hazardousness (0≤H≤1) of an activity (infrastructural development, industrial activities, livestock and agriculture) measured by a European Commission approach. The diagram is divided into four regions, the boundaries of which are set to V = 0.5 and H = 0.5. Watersheds are represented in this diagram considering their V and H indices, and assigned a potential contamination risk if groundwater sites located within their limits show contaminant concentrations above legal limits for a given use. Depending on the region the watershed falls in the L-Matrix diagram, different management or contamination prevention actions are highlighted: activity development, activity monitoring, activity planning or activity inspecting. Watersheds located in the inspecting region and simultaneously evidencing contamination risk require immediate action, namely conditioning or even suspension of use. The method is tested in the Paraopeba River basin (Minas Gerais, Brazil), a densely industrialized basin that was recently affected by an iron-ore mine tailings dam break.•The L-Matrix diagram highlights different groundwater susceptibility realities experienced by watersheds with different combinations of aquifer vulnerability and activity hazardousness, namely possibility for potential expansion of new hazardous activities but also the necessity to periodically inspect and eventually condition or suspend others.•The L-Matrix diagram is likely a better approach to implement contamination prevention measures in watersheds, than the integrated contamination risk index used by most methods.

A partial least squares-path model of environmental degradation in the Paraopeba River, for rainy seasons after the rupture of B1 tailings dam, Brumadinho, Brazil.

The present study aimed to investigate the rupture of B1 tailings dam of Córrego do Feijão mine, which drastically affected the region of Brumadinho (Minas Gerais, Brazil). The contamination of water resources reached 155.3 km from the dam site. In the river channel, high concentrations of Mn, Al, As and Fe were detected and correlated to the spillage of the tailings in the river. The presence of the tailings also affected the chlorophyll-a content in the water, as well as the reflectance of riparian forests. With the increase of metal(oid) concentrations above permitted levels, water management authorities suspended the use of Paraopeba River as resource in the impacted areas, namely the drinking water supply to the Metropolitan region of Belo Horizonte. This study aimed to evaluate possible links between tailings distribution, river water quality, and environmental degradation, which worked as latent variables in partial least squares regression models. The latent variables were represented by numerous physical and chemical parameters of water and sediment, measured four times in 22 locations during the rainy season of 2019, in addition to stream flow and to NDVI evaluated in satellite images processed daily. The modeling results suggested a relationship between river flow turbulence and increased arsenic release from sand fractions, as well as desorption of Mn from metal oxides, both representing causes of water quality reduction. They also revealed increasing iron concentrations affecting the forest NDVI (greening), which was interpreted as environmental degradation. The increase of chlorophyll-a concentrations (related with turbidity decreases), as well as the increase of river flows (responsible for dilution effects), seemed to work out as attenuators of degradation. Although applied to a specific site, our modeling approach can be transposed to equivalent dam failures and climate contexts, helping water resource management authorities to decide upon appropriate recovery solutions.

A groundwater security model based on hydraulic turnover times and flow compartments.

Starting with a log-linear relationship between groundwater discharge per unit drainage area (Q/A b), hydraulic turnover time (t) and aquifer mobile storage (z), this study builds a groundwater security method at catchment scale. The method embeds previously published approaches to calculate Q/A b, t and z, and relies solely on stream flow discharges and watershed areas. The ability to build a method on a couple of variables is remarkable. The method recasts the calculated variables as aquifer security indicators (S Q, S t and S z), relating S Q with yield capacity, S t with self-depuration capacity and S z with resilience. Groundwater security is the weighted product of S Q, S t and S z. The method is validated with stream flow discharges and drainage areas concerning 294 hydrometric stations and their watersheds, located in continental Portugal. The results revealed a majority of moderately to highly secure watersheds, especially as regards S t (> 62%), while 7-10% were classified as very highly secured in general (S Q-S t-S z). The least secured basins are located in the more arid regions of continental Portugal (Northeast and south regions), as expected. The method can be easily transposed to any other region worldwide, with the necessary adaptions to regional climate, geological and topographic settings. • Compile stream flow discharge data and organize them as natural logarithms and logarithmic variations as function of time, to estimate Q, t and z; • Recast the Q, t and z values as S Q, S t and S z ratings, respectively, using the appropriate reclassification scales, and estimate watershed security levels, namely average security or customized (weighted) securities that highlight the contributions of Q/A b (watershed yield), t (aquifer's self-depuration capacity) or z (aquifer's resilience); • Use the results to draw illustrative diagrams and spatial distribution maps.

Spatial indicator of priority areas for the implementation of agroforestry systems: An optimization strategy for agricultural landscapes restoration.

The ecological functions restoration in agricultural areas is a major challenge on a landscape scale. In the specific case of active restoration through Agroforestry Systems (AFS), the absence of a specific direction hinders ecological restoration processes, especially in regions that prefer intensive agriculture. Thus, this study aims to develop a Spatial Indicator of Priority Areas to guide Agroforestry Systems implementation in agricultural landscapes. A spatial multicriteria decision analysis (MDCA) was carried out based on environmental factors: soil, geology and slope (which determine the natural vulnerability of the land) and anthropogenic factors: land use and land cover, forest fragments, potential land use capacity and legal protected areas in rural properties (which reflects human pressure and land use suitability). Subsequently, four priority levels were classified for agroforestry interventions: (1) Low priority; (2) Average priority; (3) High priority; (4) Extreme priority. A final map was made to identify priority areas for landscape recovery in 9 cities located at the mouth of the Mogi Guaçu River Hydrographic Basin, State of São Paulo, Brazil. Considering the natural vulnerability of the land and the multifunctional aspects of the landscape, the scenarios projection allowed a consensus for forest conservation and agricultural suitability perspectives. A final combination of the explored aspects culminated in the spatial indicator, which model foresees 22,300 ha available for urgent actions for restoration, reforestation and sustainable exploitation through agroforestry systems. We emphasize the challenges in reconciling the socioeconomic and ecological functions in the agroecosystem, however, the metric provides a more inclusive and assertive management strategy for natural resources and advances towards the goal of reforestation and implementation of payment for environmental services (PES) schemes.

Water security threats and challenges following the rupture of large tailings dams.

The rupture of mine-tailings dams can severely contaminate rivers, because released tailings can interact with water for years keeping contaminant concentrations high. The general purpose of this study was to examine the rupture of B1 tailings dam in Ferro-Carvão stream (municipality of Brumadinho, state of Minas Gerais, Brazil), which occurred in 25 January 2019 and contaminated the main water course (Paraopeba River) with 2.8 Mm3 of metal-rich tailings. The specific purpose was to assess the percentage of non-conforming concentrations following the event, considering the Normative Deliberation COPAM/CERH-MG no. 1. The results showed non-conforming aluminum, iron, manganese, lead, phosphorus and turbidity concentrations, clearly above pre-rupture averages, especially in the rainy period. The catastrophe triggered the suspension of Paraopeba River as drinking water source to the Metropolitan Region of Belo Horizonte (BHMR; 6 million people). Since then, the supply to the BHMR became an everyday challenge to water management authorities, because the Paraopeba source represented a 30% share. Mitigation measures are therefore urgently needed. As complementary objective to this study, we aimed to verify the possibility to restore drinking water supply through conventional treatment. The treatability of Paraopeba River water was assessed by the Raw Water Quality Index considering the rainy and dry periods in separate. The results suggested the possibility to lift up the suspension in the dry period, improving the regional water security. Considering the huge dataset on which this study is standing, our results are generalizable to similar events with sparser information.

A partial least squares-path model of causality among environmental deterioration indicators in the dry period of Paraopeba River after the rupture of B1 tailings dam in Brumadinho (Minas Gerais, Brazil).

This study investigated the collapse of B1 mine-tailings dam that occurred in 25 January 2019 and severely affected the Brumadinho region (Minas Gerais state, Brazil) socially, economically and environmentally. As regards water resources, the event impacted the Paraopeba River in the first 155.3 km counted from the dam site, meaning nearly half the main water course downstream of B1. In the impacted sector, high concentrations of tailings-related Al, Fe, Mn, P in river sediment-tailings mixtures and water were detected, as well as changes to the reflectance of riparian forests. In the river water, the metal concentrations raised significantly above safe levels. For caution, the water management authorities declared immediate suspension of Paraopeba River as drinking water source to the Metropolitan Region of Belo Horizonte (6 million people), irrespective of representing nearly 30% of all supply. In this study, the main purpose was to assess potential links between tailings distribution, river water composition and reflectance of forest vegetation, which worked out as latent variables in regression models. The latent variables were represented by numerous physical and chemical parameters, measured 4 times in 22 sites during the dry period of 2019. The modeling results suggested the release of aluminum and phosphorus from sand fractions in the mine tailings as major cause of water contamination. The NDVI changes were interpreted as environmental deterioration. Changes in redox potential may have raised manganese concentrations in surface water further affecting the forest NDVI. Distance from the B1 dam and dissolved calcium appear to attenuate deterioration. Overall, the regressions allowed robust prognoses of environmental deterioration in the Paraopeba River under low flow conditions. More importantly, they can be transposed to similar dam ruptures helping environmental authorities to decide upon measures that can bring the affected rivers to pre-rupture conditions.

Prognosis of metal concentrations in sediments and water of Paraopeba River following the collapse of B1 tailings dam in Brumadinho (Minas Gerais, Brazil).

In January 25, 2019, the B1 dam of Córrego do Feijão mine located in Brumadinho municipality (Minas Gerais, Brazil) collapsed and injected nearly 2.8 Mm3 of iron (Fe)- and manganese (Mn)-rich tailings in the Paraopeba River. This study assessed the contribution of tailings to the contamination of sediments and water by those metals. The dataset was built through daily to weekly samplings executed in the two years following the event, at 27 sites located along the Paraopeba plus 9 sites located at the confluence of main tributaries. The results evidenced a distinct contribution in the sectors "Anomalous" (8.6-63.3 km downstream from the dam) and "Natural" (115.8-341.6 km). The "Anomalous" sector presented large Fe/Al (12.2 ± 6.4) and Mn/Al (0.33 ± 0.19) ratios in sediments, thus being rich in tailings, while the "Natural" sector presented small ratios (2.4 ± 1.0; 0.06 ± 0.03) comparable to the natural sediments. A 500-700 m3/s stream flow discharge in the Paraopeba caused pronounced drops to the Fe/Al and Mn/Al ratios in the "Anomalous" sector, attributed to the mixture of contaminated sediments from the main water course with uncontaminated sediments injected by the tributaries during the event. Non-linear regressions showed Fe/Al and Mn/Al declines in the "Anomalous" sector, related with tailings mobilization downstream. The concentrations of Fe and Al in the sediments correlated positively with the corresponding concentrations in the Paraopeba water, conditioned by raising discharge rates and variations in the water pH. The contribution of tailings to the Fe correlation was demonstrated. No direct relation was established between the Mn concentrations in water and stream discharge, because manganese is associated with fine particles in the tailings that are mobilized to the water column even under low flows. The preliminary results of Seasonal Autoregressive Integrated Moving Average models predicted the return of Paraopeba to a pre-collapse condition in 7-11 years.

Production of clean water in agriculture headwater catchments: A model based on the payment for environmental services.

This study aimed to present a payment for ecosystem services model that promotes a symbiotic coexistence between agriculture and clean water production. The model favors application to headwater catchments where clean water production is expected. However, the frequent invasion of these areas with intensive agriculture and livestock production systems affects water quality threatening the use of this resource, namely as drinking water. The proposed Agriculture for Clean Water Yield (ACWY) model reconciles agriculture with clean water production through the incentive approach, giving the farmers a financial compensation if they are willing to replace intensive by sustainable agriculture and livestock production systems, namely agro-forestry systems. The reconciliation through the incentive approach is justified because clean water and food are both vital goods for human survival. The compensation rises as function of increasing catchment water yield capacity and conversion costs. For example, landowners receive more if land conversion occurs in slopping than undulated landscapes. The model applied to Fazenda Glória watershed, composed of 19 headwater catchments (96.7 ha on average), proposed financial incentives in the range 218.73-576.5 US$/ha/year depending on the catchment's water yield capacity, which rise to 284.35-749.45 US$/ha/year if conversions occur in extreme vulnerable areas. The watershed, located in São Paulo state, Brazil, covers 18.4 km2 and is the source of drinking water to 70,000 people living in Jaboticabal city. Monitoring is essential to assess the performance of ACWY and adjust the compensation dynamically. For instance, noteworthy improvements in water yields and water quality or land conversions performed in short periods can expect the most generous compensation. Two concerns about implementing the model in Fazenda Glória rely on the lack of political will in spite of existing federal and state legal support, as well as on the financial sources to make the model a real project.

A case study of factors controlling water quality in two warm monomictic tropical reservoirs located in contrasting agricultural watersheds.

The integration of internal (e.g., stratification) and external (e.g., pollution) factors on a comprehensive assessment of reservoir water quality determines the success of ecosystem restoration initiatives and aids watershed management. However, integrated analyses are scarcer than studies addressing factors separately. Integration is likely more efficient in studies of small well-characterized (experimental) reservoir watersheds, because the isolation of factor contributions is presumably clearer. But those studies are uncommon. This work describes the water quality of two small 5.5 m-deep reservoirs (MD-Main and VD-Voçoroca dams) located in Pindorama Experimental Center, state of São Paulo, Brazil, considering the interplay between reservoir dimension, seasonal thermal stratification, chemical gradients, erosive rainfall events, presence of natural biofilters, and land uses and landscape patterns around the reservoirs and within the contributing watersheds. The monitoring of agricultural activities and water quality parameters occurred in October 2018-July 2019. A 4 °C thermal stratification occurred in October (difference between surface and bottom water temperature), which decreased until disappearance in January (VD) or April (MD). The longer stratification period of MD was justified by its larger area relative to VD (≈10×). Thermal stratification triggered hypoxia at the bottom of both reservoirs (DO ≈ 1 mg/L), more prolonged and severe in MD. Hypoxia activated Ec and TDS peaks in January likely explained by bottom-sediment nutrient releases, presumably phosphorus. The Ec peak reached 560 µS/cm in MD and 290 µS/cm in VD. The smaller VD peak was probably explained by the action of macrophytes. In March, a 240 NTU turbidity peak occurred in MD, caused by precedent erosive rainfall and the lack of vegetation protection alongside the south border. As expected, the study accomplished clear isolation of factor contributions, verified by Factor and Cluster analyses. Our results can subsidize studies on larger reservoir watersheds requiring restoration, where the isolation of factors is more challenging.

Conflito de uso e indicadores morfométricos para a gestão de política de uso do solo / Land use conflict and morphometric indicators for land use policy management

RESUMO Este trabalho propõe indicadores ambientais de políticas públicas com base na espacialização dos parâmetros morfométricos e de conflito de uso em áreas municipais. As técnicas de geoprocessamento de imagens orbitais em sistemas de informações geográficas foram utilizadas para analisar o banco de dados dos valores de cada parâmetro morfométrico da superfície terrestre - área, perímetro, comprimento da rede de drenagem, densidade de drenagem, número de canais, frequência de rios, declividade e coeficiente de rugosidade - e elaborar os mapas temáticos de uso atual, de uso potencial e de conflito de uso do solo. Os dados foram submetidos à análise estatística descritiva e exploratória multivariada. A espacialização dos valores obtidos da caracterização morfométrica gerou indicadores físicos ambientais que possibilitaram a diferenciação de áreas. O conhecimento do sistema hidrológico dessas regiões reflete o sistema natural de drenagem em seu comprimento. O número de canais e conflito de uso indicam áreas prioritárias para gestão ambiental e políticas de uso do solo. Os parâmetros morfométricos são potenciais indicadores ambientais.

ABSTRACT This study has the main objective to propose environmental indicators for public policies based on spatial distribution of morphometric characteristics and land-use conflicts in municipal areas. The techniques of satellite images in geographic information systems were used to analyze the database of the values of each morphometric parameter of the earth's surface: area, perimeter, length of the drainage system, drainage density, number of channels, river frequency, slope and roughness coefficient and to elaborate thematic maps of current land-use, potential land-use, and land-use conflicts. The data were submitted to descriptive and multivariate exploratory statistical analysis. The spatial distribution of values of morphometric characterization generated environmental physical indicators which enabled the differentiation of areas. The knowledge of the hydrological system in these regions reflects the natural drainage system along its length. The number of channels and the land-use conflicts indicate priority areas for environmental management and land use policies. The morphometric characteristics are potential environmental indicators.

Land use impact on potentially toxic metals concentration on surface water and resistant microorganisms in watersheds.

Soil and water resources must be conserved and protected. However, the management of production activities causes a change in the quality of these natural resources due to accumulation in soil of potentially toxic metals. The objective of the present study was to identify the variety and paths of potentially toxic metals (PTMs), such as cadmium, lead, copper, chromium, nickel and zinc, which are associated spatially and temporally to soil and water. We also intended to isolate bacteria resistant to PTMs with important characteristics to be used in bioremediation processes. Water samples were collected every two months for one year (February-December/2014) at eight sites (P1-P8) and the soil samples were collected twice (February and August/2014) from twelve sites (S1-S12). Results indicated that agricultural land use impacts the environment, increasing the concentration of potentially toxic metals, mainly copper, zinc and chromium, in soil and water due to crop management. Ten bacteria resistant to all the metals studied were isolated, which could be used as tools for bioremediation of contaminated soils and water with those metals. The results would positively contribute to land use policy, and for the development of enhanced agricultural practices.

Diagnosis on Transport Risk Based on a Combined Assessment of Road Accidents and Watershed Vulnerability to Spills of Hazardous Substances.

Roads play an important role in the economic development of cities and regions, but the transport of cargo along highways may represent a serious environmental problem because a large portion of transported goods is composed of dangerous products. In this context, the development and validation of risk management tools becomes extremely important to support the decision-making of people and agencies responsible for the management of road enterprises. In the present study, a method for determination of environmental vulnerability to road spills of hazardous substances is coupled with accident occurrence data in a highway, with the purpose to achieve a diagnosis on soil and water contamination risk and propose prevention measures and emergency alerts. The data on accident occurrences involving hazardous and potentially harmful products refer to the highway BR 050, namely the segment between the Brazilian municipalities of Uberaba and Uberlândia. The results show that many accidents occurred where vulnerability is high, especially in the southern sector of the segment, justifying the implementation of prevention and alert systems. The coupling of vulnerability and road accident data in a geographic information system proved efficient in the preparation of quick risk management maps, which are essential for alert systems and immediate environmental protection. Overall, the present study contributes with an example on how the management of risk can be conducted in practice when the transport of dangerous substances along roads is the focus problem.